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Nitrile oxides are oxidized by tertiary amine N-oxides in different solvents at room temperature to afford in the presence of dienes nitrosocarbonyl adducts in fair yields. The mild conditions used in oxidizing a variety of nitrile oxides promise a wide application of this method in synthetic processes.

The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses

CARAMELLA, PIERLUIGI;MELLA, MARIELLA;QUADRELLI, PAOLO;
1999-01-01

Abstract

Nitrile oxides are oxidized by tertiary amine N-oxides in different solvents at room temperature to afford in the presence of dienes nitrosocarbonyl adducts in fair yields. The mild conditions used in oxidizing a variety of nitrile oxides promise a wide application of this method in synthetic processes.
1999
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
TETRAHEDRON
sì
000081932100020
2-s2.0-0033588294
Esperti anonimi
Inglese
Internazionale
STAMPA
55
34
10497
10510
14
Tematica Ex SIR: Reazioni pericicliche. Studio delle selettivit` delle cicloaddizioni 1,3-dipolari, dieniche ed eniche e chimismo degli addotti (Classif. Ex SIR:Articoli su riviste ISI )
Diels-Alder reactions; nitrile oxides; nitroso compounds; N-oxides; solvents
4
info:eu-repo/semantics/article
262
Caramella, Pierluigi; Mella, Mariella; Quadrelli, Paolo; Gamba, Anna
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/4079
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