Time-resolved laser spectroscopy has been used to generate and characterize a series of tertiary amine cation radicals and to det. the rates of their α-CH deprotonation and α-desilylation reactions with bases and silophiles

Dynamics of α-CH Deprotonation and α-Desilylation Reactions of Tertiary Amine Cation Radicals

FRECCERO, MAURO;ALBINI, ANGELO;
1994-01-01

Abstract

Time-resolved laser spectroscopy has been used to generate and characterize a series of tertiary amine cation radicals and to det. the rates of their α-CH deprotonation and α-desilylation reactions with bases and silophiles
1994
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
116
4211
4220
Cation Radicals; Laser Flash Photolysis
8
info:eu-repo/semantics/article
262
Zhang, Xiaoming; Yeh, ; Syun Ru, Hong; Seok, ; Freccero, Mauro; Albini, Angelo; Falvey Daniel, E.; Mariano Patrick, S.
1 Contributo su Rivista::1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/439615
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