Chloranil (Chl) has been irradiated in the presence of the alkanes 2,3-dimethylbutane, cyclohexane, norbornane, adamantane in acetonitrile. The primary step is hydrogen abstraction by triplet Chl, as confirmed by the detection of the ChlH radical. Hydrogen abstraction from the alkanes is unselective.
The photochemical approach to the functionalization of open-chain and cyclic alkanes: 2. Hydrogen abstraction
MELLA, MARIELLA;FRECCERO, MAURO;ALBINI, ANGELO
1996-01-01
Abstract
Chloranil (Chl) has been irradiated in the presence of the alkanes 2,3-dimethylbutane, cyclohexane, norbornane, adamantane in acetonitrile. The primary step is hydrogen abstraction by triplet Chl, as confirmed by the detection of the ChlH radical. Hydrogen abstraction from the alkanes is unselective.File in questo prodotto:
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