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Zn-II coordination by the tetraamine spacer of the two-component system 1 brings the dimethylaniline fragment (donor) and the anthracene subunit (fluorophore) close enough to allow a photoinduced electron-transfer (PET) process to take place. Transition metals (e.g. Cu-II, Ni-II) quench the fluorophore, preventing intramolecular PET.

A zinc(II)-driven intramolecular photoinduced electron transfer

FABBRIZZI, LUIGI;LICCHELLI, MAURIZIO;PALLAVICINI, PIERSANDRO;TAGLIETTI, ANGELO MARIA
1996-01-01

Abstract

Zn-II coordination by the tetraamine spacer of the two-component system 1 brings the dimethylaniline fragment (donor) and the anthracene subunit (fluorophore) close enough to allow a photoinduced electron-transfer (PET) process to take place. Transition metals (e.g. Cu-II, Ni-II) quench the fluorophore, preventing intramolecular PET.
1996
The Chemistry category includes resources that are general in nature and cover a broad spectrum of topics in the chemical sciences. Resources specifically covering analytical chemistry, inorganic and nuclear chemistry, organic chemistry, physical chemistry, and polymer science will be placed in those particular categories. Miscellaneous and applied chemistry resources may be placed in this category when not appropriate for specific subfields in chemistry.
INORGANIC CHEMISTRY
sì
WOS:A1996UA16900055
2-s2.0-0000239876
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
35
6
1733
1736
ELECTRON TRANSFER; ZINC(II) COMPLEXES; POLYAMINO LIGANDS
4
info:eu-repo/semantics/article
262
Fabbrizzi, Luigi; Licchelli, Maurizio; Pallavicini, Piersandro; Taglietti, ANGELO MARIA
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/442340
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