Cyclic voltammetric scans for methylarsonic acid, dimethylarsinic acid and 3-acetamido-4-hydroxyphenylarsonic acid at amercuryelectrode in an acidic medium show anodic adsorption waves when the starting potential is sufficiently negative; the related arsines are formed on the electrode. Detection limits are at the micromolar level for the absorption peak found at about −0.1 V vs. SCE for all three compounds. Interferences are discussed.

VOLTAMMETRIC DETERMINATION OF SOME ORGANIC COMPOUNDS OF ARSENIC REDUCED AT THE MERCURY ELECTRODE

SPINI, GIOVANNI;PROFUMO, ANTONELLA;SOLDI, TERESA
1985

Abstract

Cyclic voltammetric scans for methylarsonic acid, dimethylarsinic acid and 3-acetamido-4-hydroxyphenylarsonic acid at amercuryelectrode in an acidic medium show anodic adsorption waves when the starting potential is sufficiently negative; the related arsines are formed on the electrode. Detection limits are at the micromolar level for the absorption peak found at about −0.1 V vs. SCE for all three compounds. Interferences are discussed.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11571/445137
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