A three-component system in which two non-equivalent ferrocene fragments are appended to a metallocyclam subunit has been prepared through an Ni(II) template synthesis. The system undergoes two distinct and consecutive reversible one-electron oxidation processes centred on the two ferrocene fragments, but decomposes on oxidation of the Ni(II) centre.

APPENDING 2 NONEQUIVALENT FERROCENE FRAGMENTS TO A METALLOCYCLAM CORE

FABBRIZZI, LUIGI;LICCHELLI, MAURIZIO;MANGANO, CARLO PAOLO;PALLAVICINI, PIERSANDRO
1993

Abstract

A three-component system in which two non-equivalent ferrocene fragments are appended to a metallocyclam subunit has been prepared through an Ni(II) template synthesis. The system undergoes two distinct and consecutive reversible one-electron oxidation processes centred on the two ferrocene fragments, but decomposes on oxidation of the Ni(II) centre.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/446138
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