A three-component system in which two non-equivalent ferrocene fragments are appended to a metallocyclam subunit has been prepared through an Ni(II) template synthesis. The system undergoes two distinct and consecutive reversible one-electron oxidation processes centred on the two ferrocene fragments, but decomposes on oxidation of the Ni(II) centre.
APPENDING 2 NONEQUIVALENT FERROCENE FRAGMENTS TO A METALLOCYCLAM CORE
FABBRIZZI, LUIGI;LICCHELLI, MAURIZIO;MANGANO, CARLO PAOLO;PALLAVICINI, PIERSANDRO
1993-01-01
Abstract
A three-component system in which two non-equivalent ferrocene fragments are appended to a metallocyclam subunit has been prepared through an Ni(II) template synthesis. The system undergoes two distinct and consecutive reversible one-electron oxidation processes centred on the two ferrocene fragments, but decomposes on oxidation of the Ni(II) centre.File in questo prodotto:
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