In the crystal structure of [Cu(C16H26N6O3)]NO32, the metal ion lies in an elongated octahedral coordination. Only the four secondary amine N atoms of the macrocycle are bound to the Cu2+ centre which resides 0.080 (1) Å out of the N4 donor plane. The coordination sphere is completed by two nitrate O atoms axially coordinated with different Cu-O distances.
(4-Nitrophenyl 1,3,5,8,12-pentaazacyclotetradec-3-yl ketone-N1,N5,N8,N12)copper(II) Dinitrate
LICCHELLI, MAURIZIO
1996-01-01
Abstract
In the crystal structure of [Cu(C16H26N6O3)]NO32, the metal ion lies in an elongated octahedral coordination. Only the four secondary amine N atoms of the macrocycle are bound to the Cu2+ centre which resides 0.080 (1) Å out of the N4 donor plane. The coordination sphere is completed by two nitrate O atoms axially coordinated with different Cu-O distances.File in questo prodotto:
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