From a purely enthalpic standpoint, the beta-CD hydration, as studied by semiempirical calculations appears improbable, in contrast to experiment. For the spontaneous hydration process, a compensation mechanism, connected to substrate stabilitazion and/or entropy increase, is suggested, on the basis of simple thermodynamic calculations.
Thermodynamics of β-Cyclodextrin/Water Interactions
MARGHERITIS, CHIARA;MARINI, AMEDEO;SINISTRI, CESARE
1997-01-01
Abstract
From a purely enthalpic standpoint, the beta-CD hydration, as studied by semiempirical calculations appears improbable, in contrast to experiment. For the spontaneous hydration process, a compensation mechanism, connected to substrate stabilitazion and/or entropy increase, is suggested, on the basis of simple thermodynamic calculations.File in questo prodotto:
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