From a purely enthalpic standpoint, the beta-CD hydration, as studied by semiempirical calculations appears improbable, in contrast to experiment. For the spontaneous hydration process, a compensation mechanism, connected to substrate stabilitazion and/or entropy increase, is suggested, on the basis of simple thermodynamic calculations.

Thermodynamics of β-Cyclodextrin/Water Interactions

MARGHERITIS, CHIARA;MARINI, AMEDEO;SINISTRI, CESARE
1997-01-01

Abstract

From a purely enthalpic standpoint, the beta-CD hydration, as studied by semiempirical calculations appears improbable, in contrast to experiment. For the spontaneous hydration process, a compensation mechanism, connected to substrate stabilitazion and/or entropy increase, is suggested, on the basis of simple thermodynamic calculations.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/451042
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