Two lactarane sesquiterpenes, furoscrobiculin D and blennin D, previously isolated from the mushrooms Lactarius scrobiculatus and Lactarius blennius, respectively, have been submitted to conformational analysis by molecular mechanics. The results of the molecular modeling were related to the observed H-1 NMR data and allowed to assign stereostructure 4 to furoscrobiculin D, correcting the previous assignment 1, and stereostructure 5 to blennin D, confirming the previous assignment.

Conformational Studies and Stereochemical Assignments of the Lactarane Sesquiterpenes Furoscrobiculin D and Blennin D

TOMA, LUCIO;VIDARI, GIOVANNI;
1994-01-01

Abstract

Two lactarane sesquiterpenes, furoscrobiculin D and blennin D, previously isolated from the mushrooms Lactarius scrobiculatus and Lactarius blennius, respectively, have been submitted to conformational analysis by molecular mechanics. The results of the molecular modeling were related to the observed H-1 NMR data and allowed to assign stereostructure 4 to furoscrobiculin D, correcting the previous assignment 1, and stereostructure 5 to blennin D, confirming the previous assignment.
1994
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
50
1211
1216
5
4
info:eu-repo/semantics/article
262
L., Garlaschelli; Toma, Lucio; Vidari, Giovanni; D., Colombo
1 Contributo su Rivista::1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/453821
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