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A regio- and stereoselective didehydrodimerization procedure, whose key step involves the anodic oxidation, allows the conversion of beta-anilinoacrylic alkaloids belonging to the Aspidosperma class, typified by tabersonine (1) and its 3-oxo derivative 2, into the hitherto unknown 16,10'-didehydro dimers 3 and 7, respectively.

Aspidosperma Alkaloids - A New Didehydrodimerization Mode of Beta-anilinoacrylic Alkaloids By Anodic-oxidation

TOMA, LUCIO
1992-01-01

Abstract

A regio- and stereoselective didehydrodimerization procedure, whose key step involves the anodic oxidation, allows the conversion of beta-anilinoacrylic alkaloids belonging to the Aspidosperma class, typified by tabersonine (1) and its 3-oxo derivative 2, into the hitherto unknown 16,10'-didehydro dimers 3 and 7, respectively.
1992
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
HELVETICA CHIMICA ACTA
sì
WOS:A1992HU38700015
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
75
813
824
11
6
info:eu-repo/semantics/article
262
G., Palmisano; B., Danieli; G., Lesma; M., Santagostino; G., Fiori; Toma, Lucio
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/453828
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