Dioxocyclam (H2L = 1,4,8,11-tetraazacyclotetradecane-5,7-dione), prepd. from di-Et malonate and 1,9-diamino-3,7-diazanonane, was reacted with Cu(OAc)2.H2O in aq. EtOH to give CuL. CuL was electrochem. or chem. (by K2S2O8) oxidized to [CuL]+.
1,4,8,11-Tetraazacyclotetradecane-5,7-dione (dioxocyclam) copper(II) and aqueous copper(III) complexes
FABBRIZZI, LUIGI;POGGI, ANTONIO;
1985
Abstract
Dioxocyclam (H2L = 1,4,8,11-tetraazacyclotetradecane-5,7-dione), prepd. from di-Et malonate and 1,9-diamino-3,7-diazanonane, was reacted with Cu(OAc)2.H2O in aq. EtOH to give CuL. CuL was electrochem. or chem. (by K2S2O8) oxidized to [CuL]+.File in questo prodotto:
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