Cu(III) complexes with the tetraazamacrocycles I and II (R = H, Me), generated electrochem. from the corresponding Cu(II) complexes, were stabilized in 10 M HClO4; the Cu(III) complex with I showed a greater stability in 10 M HClO4 than the corresponding Ni(III) complex, an inversion of the normally obsd. trend.
Stabilization by a strongly acidic medium of trivalent copper tetraaza macrocyclic complexes
FABBRIZZI, LUIGI;LICCHELLI, MAURIZIO;POGGI, ANTONIO
1984-01-01
Abstract
Cu(III) complexes with the tetraazamacrocycles I and II (R = H, Me), generated electrochem. from the corresponding Cu(II) complexes, were stabilized in 10 M HClO4; the Cu(III) complex with I showed a greater stability in 10 M HClO4 than the corresponding Ni(III) complex, an inversion of the normally obsd. trend.File in questo prodotto:
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