The oxidn. and redn. of Cu(II) complexes with the tetra- and pentadentate amine macrocycles I (n-n2 = 0, 1) and II (n-n2 = 0; n = 1, n1 ≠ n2 = 1, 0) in CH3CN were studied by electrochem. methods. The redox changes Cu(III) → Cu(II) and Cu(II) → Cu(I) were detected through cyclic voltammetry at high potential scan rates. The half-wave potentials are discussed in terms of the properties and structural features of the macrocyclic ligands.
Oxidation and reduction of copper(II) complexes with saturated polyaza macrocycles of varying size and denticity
FABBRIZZI, LUIGI;POGGI, ANTONIO;
1983-01-01
Abstract
The oxidn. and redn. of Cu(II) complexes with the tetra- and pentadentate amine macrocycles I (n-n2 = 0, 1) and II (n-n2 = 0; n = 1, n1 ≠ n2 = 1, 0) in CH3CN were studied by electrochem. methods. The redox changes Cu(III) → Cu(II) and Cu(II) → Cu(I) were detected through cyclic voltammetry at high potential scan rates. The half-wave potentials are discussed in terms of the properties and structural features of the macrocyclic ligands.File in questo prodotto:
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