[Cu(III)L]+ and [Ni(III)L(H2O)2]+ (L = I) were prepd. from the Cu(II) and Ni(II) analogs by, chem. (K2S2O8) or anodic (Pt gauze electrode, ∼0.8 V vs. SCE) oxidn. The aq. complexes were unstable, decompg. during a few h at room temp. The oxidn. state was detd. by voltammetric and ESR studies. The stabilities of the complexes are discussed relative to those of the tetraamine macrocycle-complexed analogs.

Aqueous copper(III) and nickel(III) tetraaza macrocyclic complexes

FABBRIZZI, LUIGI;POGGI, ANTONIO
1980

Abstract

[Cu(III)L]+ and [Ni(III)L(H2O)2]+ (L = I) were prepd. from the Cu(II) and Ni(II) analogs by, chem. (K2S2O8) or anodic (Pt gauze electrode, ∼0.8 V vs. SCE) oxidn. The aq. complexes were unstable, decompg. during a few h at room temp. The oxidn. state was detd. by voltammetric and ESR studies. The stabilities of the complexes are discussed relative to those of the tetraamine macrocycle-complexed analogs.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/455640
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 56
  • ???jsp.display-item.citation.isi??? ND
social impact