A review with 42 refs. The tendency to stabilize trivalent cations, which is expressed by the value of the M3+/M2p redox potential (M = Cu, Ni, etc.), is regulated by the structural features of the macrocycle (ring size, no. and type of donor N atm.). Axial coordination of the solvent, equatorial interactions, and ligand field contributions are discussed.

The stabilization of high oxidation states of metals through coordination by poly-aza macrocycles

FABBRIZZI, LUIGI
1985-01-01

Abstract

A review with 42 refs. The tendency to stabilize trivalent cations, which is expressed by the value of the M3+/M2p redox potential (M = Cu, Ni, etc.), is regulated by the structural features of the macrocycle (ring size, no. and type of donor N atm.). Axial coordination of the solvent, equatorial interactions, and ligand field contributions are discussed.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/462080
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