The oxidn. of (1,4,7,10,13-pentaazacyclohexadecane)nickel(II) by OH• in aq. solns. was studied, and the properties of the resulting Ni(III) complex were compared with those of [NiL]3+ (L = tetraazacyclotetradecane). The difference in the properties is attributed to the 5th N donor atom which decreases the activity of the central tervalent Ni.
Properties of (1,4,7,10,13-pentaazacyclohexadecane)nickel(III) in aqueous solutions: a pulse radiolytic study
FABBRIZZI, LUIGI;
1983-01-01
Abstract
The oxidn. of (1,4,7,10,13-pentaazacyclohexadecane)nickel(II) by OH• in aq. solns. was studied, and the properties of the resulting Ni(III) complex were compared with those of [NiL]3+ (L = tetraazacyclotetradecane). The difference in the properties is attributed to the 5th N donor atom which decreases the activity of the central tervalent Ni.File in questo prodotto:
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