The heat of formation of complex I (n = 2, m = 3) exceeds that of I (n = 3, m = 2), which in turn exceeds that of the fused system II. These effects are caused by deformations in the macrocyclic framework, resulting in decreases in the in-plane Cu-N interactions.

Enthalpy of formation of copper(II) complexes with 14-membered tetraaza macrocycles

FABBRIZZI, LUIGI;
1978-01-01

Abstract

The heat of formation of complex I (n = 2, m = 3) exceeds that of I (n = 3, m = 2), which in turn exceeds that of the fused system II. These effects are caused by deformations in the macrocyclic framework, resulting in decreases in the in-plane Cu-N interactions.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/464608
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