The heat of formation of complex I (n = 2, m = 3) exceeds that of I (n = 3, m = 2), which in turn exceeds that of the fused system II. These effects are caused by deformations in the macrocyclic framework, resulting in decreases in the in-plane Cu-N interactions.
Enthalpy of formation of copper(II) complexes with 14-membered tetraaza macrocycles
FABBRIZZI, LUIGI;
1978-01-01
Abstract
The heat of formation of complex I (n = 2, m = 3) exceeds that of I (n = 3, m = 2), which in turn exceeds that of the fused system II. These effects are caused by deformations in the macrocyclic framework, resulting in decreases in the in-plane Cu-N interactions.File in questo prodotto:
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