The thermodn. function ΔH° and ΔS° for the reaction of biguanide with Ni(II) and Cu(II) ions in 0.1 M KCl were detd. at 25°. The reaction is strongly exothermic with the formation of 1:2 metal-ligand complexes. The ligand stabilization due to π-delocalization and formation of metal-N bonds are both responsible for the high exothermic effect of the complex formation.
Thermochemical consequences of π delocalization in metal-biguanide complexes
FABBRIZZI, LUIGI;
1978-01-01
Abstract
The thermodn. function ΔH° and ΔS° for the reaction of biguanide with Ni(II) and Cu(II) ions in 0.1 M KCl were detd. at 25°. The reaction is strongly exothermic with the formation of 1:2 metal-ligand complexes. The ligand stabilization due to π-delocalization and formation of metal-N bonds are both responsible for the high exothermic effect of the complex formation.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
