Free energies, enthalpies, and entropies of formation of Ni(II), Cu(II), Zn(II), and proton complexes of H2N(CH2)2NH(CH2)3NH(CH2)2NH2 were detd. calorimetrically at 25°. The high stability of the metal complexes was due to the enthalpy term even when the entropy term was favorable.
Thermodynamics of complex formation with linear aliphatic tetramines. II. Heats and entropies of the reactions of 3,7-diaza-1,9-nonane-1,9-diamine with hydrogen ions and bivalent transition-metal ions
FABBRIZZI, LUIGI;
1972-01-01
Abstract
Free energies, enthalpies, and entropies of formation of Ni(II), Cu(II), Zn(II), and proton complexes of H2N(CH2)2NH(CH2)3NH(CH2)2NH2 were detd. calorimetrically at 25°. The high stability of the metal complexes was due to the enthalpy term even when the entropy term was favorable.File in questo prodotto:
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