Bicyclo[3.1.0]hex-2-ene radicalcation, generated by γ-irradiation of the parent compound in freon matrices at 77 K, undergoes ring opening to the 1,3-cyclohexadiene radicalcation. In CF2ClCFCl2 matrix both radicalcations also undergo deprotonation to the corresponding neutral radicals.
ESR Study of radical cations from γ-irradiation of bicyclo[3.1.0]hex-2-ene in freon matrices
FAUCITANO, ANTONIO;BUTTAFAVA, ARMANDO;MARTINOTTI, FAUSTA;
1992-01-01
Abstract
Bicyclo[3.1.0]hex-2-ene radicalcation, generated by γ-irradiation of the parent compound in freon matrices at 77 K, undergoes ring opening to the 1,3-cyclohexadiene radicalcation. In CF2ClCFCl2 matrix both radicalcations also undergo deprotonation to the corresponding neutral radicals.File in questo prodotto:
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