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Bicyclo[3.1.0]hex-2-ene radicalcation, generated by γ-irradiation of the parent compound in freon matrices at 77 K, undergoes ring opening to the 1,3-cyclohexadiene radicalcation. In CF2ClCFCl2 matrix both radicalcations also undergo deprotonation to the corresponding neutral radicals.

ESR Study of radical cations from γ-irradiation of bicyclo[3.1.0]hex-2-ene in freon matrices

FAUCITANO, ANTONIO;BUTTAFAVA, ARMANDO;MARTINOTTI, FAUSTA;
1992-01-01

Abstract

Bicyclo[3.1.0]hex-2-ene radicalcation, generated by γ-irradiation of the parent compound in freon matrices at 77 K, undergoes ring opening to the 1,3-cyclohexadiene radicalcation. In CF2ClCFCl2 matrix both radicalcations also undergo deprotonation to the corresponding neutral radicals.
1992
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
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Inglese
Internazionale
STAMPA
33
2223
2226
4
5
info:eu-repo/semantics/article
262
Faucitano, Antonio; Buttafava, Armando; Martinotti, Fausta; R., Sustmann; H. G., Korth
1 Contributo su Rivista::1.1 Articolo in rivista
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1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/468832
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