The anisotropic components of the α and β Fluorine h.f. tensors of alkoxyfluoroalkyl radicals ROCF2 and ROCF(CF3) were experimentally determined and basic informations pertaining the geometry of the radical centres and the mechanism of magnetic interactions were obtained. The structure of RfOCF2 and RfOCF(CF2) is determined by solid state ESR.
Alkoxyfluoroalkyl radicals: Structure and conformations from solid state esr spectra
FAUCITANO, ANTONIO;BUTTAFAVA, ARMANDO;MARTINOTTI, FAUSTA;
1988-01-01
Abstract
The anisotropic components of the α and β Fluorine h.f. tensors of alkoxyfluoroalkyl radicals ROCF2 and ROCF(CF3) were experimentally determined and basic informations pertaining the geometry of the radical centres and the mechanism of magnetic interactions were obtained. The structure of RfOCF2 and RfOCF(CF2) is determined by solid state ESR.File in questo prodotto:
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