Benzyl Et sulfideis photo-oxidized to benzaldehyde in benzene, whereas di-Et sulfide is known to give inefficiently the sulfoxide under these conditions. Oxidative C-S cleavage is the main process also with benzhydryl Et sulfide, but not with α-methylbenzyl Et sulfide, which mainly gives the sulfoxide. The carbonyl derivs. reasonably arise from S-hydroperoxy ylide.
Photosensitized oxygenation of some benzyl sulfides. The role of persulfoxide
FRECCERO, MAURO;ALBINI, ANGELO
1999-01-01
Abstract
Benzyl Et sulfideis photo-oxidized to benzaldehyde in benzene, whereas di-Et sulfide is known to give inefficiently the sulfoxide under these conditions. Oxidative C-S cleavage is the main process also with benzhydryl Et sulfide, but not with α-methylbenzyl Et sulfide, which mainly gives the sulfoxide. The carbonyl derivs. reasonably arise from S-hydroperoxy ylide.File in questo prodotto:
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