IRIS

In this paper we describe the synthesis and intercomparison of several new methanofullerenes, each bearing a macrocyclic crown ether containing a malonate moiety directly attached to the C-60-fullerene core. Their complexing abilities with primary alkylammonium ions were investigated by NMR and mass spectrometry, and also by transport experiments through a liquid membrane. We also report on their electrochemical behaviour, together with EPR analysis of their supramolecular complexes with alkyl ammonium molecules labelled with a stable nitroxide radical.

Methanofullerenes from Macrocyclic Malonates

GARLASCHELLI, LUIGI;PASINI, DARIO;RIGHETTI, PIER PAOLO;
2003-01-01

Abstract

In this paper we describe the synthesis and intercomparison of several new methanofullerenes, each bearing a macrocyclic crown ether containing a malonate moiety directly attached to the C-60-fullerene core. Their complexing abilities with primary alkylammonium ions were investigated by NMR and mass spectrometry, and also by transport experiments through a liquid membrane. We also report on their electrochemical behaviour, together with EPR analysis of their supramolecular complexes with alkyl ammonium molecules labelled with a stable nitroxide radical.
2003
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
sì
WOS:000180503500019
2-s2.0-0037238839
Esperti anonimi
Inglese
Internazionale
STAMPA
374
384
11
FULLERENES; CROWN ETHERS; EPR SPECTROSCOPY; MOLECULAR RECOGNITION; SUPRAMOLECULAR CHEMISTRY
10
info:eu-repo/semantics/article
262
Carano, Maurizio; Corvaja, Carlo; Garlaschelli, Luigi; Maggini, Michele; Marcaccio, Massimo; Paolucci, Francesco; Pasini, Dario; Righetti, PIER PAOLO;...espandi
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/131528
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 20
  • ???jsp.display-item.citation.isi??? 18
social impact