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The hydroalkylation of nitroalkenes and β-nitroacrylates via a photocatalytic strategy has been optimised under both batch and continuous flow conditions. This target has been achieved by exploiting the potentialities of the decatungstate anion as a versatile hydrogen atom transfer (HAT) photocatalyst for the generation of alkyl radicals from aliphatic heterocycles, amides and cycloalkanes.

More Chips to Nitroolefins: Decatungstate Photocatalysed Hydroalkylation Under Batch and Flow Conditions

Alexandra Jorea;Benedetta Bassetti;Stefano Protti;Alessandro Palmieri
;Davide Ravelli
2023-01-01

Abstract

The hydroalkylation of nitroalkenes and β-nitroacrylates via a photocatalytic strategy has been optimised under both batch and continuous flow conditions. This target has been achieved by exploiting the potentialities of the decatungstate anion as a versatile hydrogen atom transfer (HAT) photocatalyst for the generation of alkyl radicals from aliphatic heterocycles, amides and cycloalkanes.
2023
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
ADVANCED SYNTHESIS & CATALYSIS
sì
WOS:000936835500001
2-s2.0-85148370669
Esperti anonimi
Inglese
Internazionale
STAMPA
365
5
722
727
6
Flow Chemistry; Hydroalkylation, Tetrabutylammonium Decatungstate (TBADT); Hydrogen Atom Transfer (HAT); Nitroalkenes; Photocatalysis
https://onlinelibrary.wiley.com/doi/10.1002/adsc.202201314
no
6
info:eu-repo/semantics/article
262
Jorea, Alexandra; Bassetti, Benedetta; Gervasoni, Klaus; Protti, Stefano; Palmieri, Alessandro; Ravelli, Davide
1 Contributo su Rivista::1.1 Articolo in rivista
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1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/1476360
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