In the cation formed by photoinduced C−F bond cleavage in fleroxacin, intramolecular reaction with the N−ethyl chain is prevented by the electron-withdrawing effect of fluorine and intermolecular attack by nucleophiles is facilitated.
Inter- and Intramolecular Photochemical Reactions of Fleroxacin.
FASANI, ELISA;TILOCCA, FEDELE;PRETALI, LUCA;MELLA, MARIELLA;ALBINI, ANGELO
2009-01-01
Abstract
In the cation formed by photoinduced C−F bond cleavage in fleroxacin, intramolecular reaction with the N−ethyl chain is prevented by the electron-withdrawing effect of fluorine and intermolecular attack by nucleophiles is facilitated.File in questo prodotto:
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