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In the cation formed by photoinduced C−F bond cleavage in fleroxacin, intramolecular reaction with the N−ethyl chain is prevented by the electron-withdrawing effect of fluorine and intermolecular attack by nucleophiles is facilitated.

Inter- and Intramolecular Photochemical Reactions of Fleroxacin.

FASANI, ELISA;TILOCCA, FEDELE;PRETALI, LUCA;MELLA, MARIELLA;ALBINI, ANGELO
2009-01-01

Abstract

In the cation formed by photoinduced C−F bond cleavage in fleroxacin, intramolecular reaction with the N−ethyl chain is prevented by the electron-withdrawing effect of fluorine and intermolecular attack by nucleophiles is facilitated.
2009
The Organic Chemistry/Polymer Science category includes resources concerned with the related fields of organic chemistry and polymer science. The organic chemistry resources deal with compounds of carbon with the exception of certain simple ones, such as the carbon oxides, carbonates, cyanides and cyanates (see Inorganic & Nuclear Chemistry). This category includes research on synthetic and natural organic compounds that may include other elements, such as hydrogen and oxygen, but also nitrogen, halogens, sulphur and phosphorous. Resources concerned with hydrocarbons, organic compounds containing only the elements carbon and hydrogen, are also included in this category. Examples are the alkanes, alkenes, alkynes and aromatics, such as benzene and naphthalene. Polymer science includes all resources dealing with the study, production and technology of polymers, which are compounds composed of very large molecules made up of repeating molecular units (monomers). Polymers may be natural substances, such as polysaccharides or proteins, or synthetic materials, such as nylon or polyethylene.
ORGANIC LETTERS
sì
Sì, ma tipo non specificato
Inglese
Internazionale
STAMPA
11
9
1875
1878
fluoroquinolones; fleroxacin; photochemistry; mechanism
7
info:eu-repo/semantics/article
262
Fasani, Elisa; Monti, Sandra; Manet, Ilse; Tilocca, Fedele; Pretali, Luca; Mella, Mariella; Albini, Angelo
1 Contributo su Rivista::1.1 Articolo in rivista
none
1.1 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/148192
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