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EnglishNMR and magnetization measurements in Li0.5MnPc (Pc=C32H16N8), recently proposed as a strongly correlated metal, are presented. Two different low-frequency dynamics are evidenced. The first one, probed by 1H nuclei, gives rise to a slowly relaxing magnetization at low temperature and is associated with the freezing of MnPc S=3/2 spins. This dynamics is similar to the one observed in pristine beta-MnPc and originates from Li-depleted chain segments. The second one, evidenced by the 7Li spin-lattice relaxation rate, is associated with the hopping of the electrons along Li-rich chains. The characteristic correlation times for the two dynamics are derived, and the role of the disorder is briefly discussed.
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| Titolo: | Low-energy excitations in the electron-doped metal phtalocyanine LiO.5MnPc from Li and 1H NMR | |
| Autori: | ||
| Data di pubblicazione: | 2007 | |
| Rivista: | ||
| Abstract: | NMR and magnetization measurements in Li0.5MnPc (Pc=C32H16N8), recently proposed as a strongly correlated metal, are presented. Two different low-frequency dynamics are evidenced. The first one, probed by 1H nuclei, gives rise to a slowly relaxing magnetization at low temperature and is associated with the freezing of MnPc S=3/2 spins. This dynamics is similar to the one observed in pristine beta-MnPc and originates from Li-depleted chain segments. The second one, evidenced by the 7Li spin-lattice relaxation rate, is associated with the hopping of the electrons along Li-rich chains. The characteristic correlation times for the two dynamics are derived, and the role of the disorder is briefly discussed. | |
| Handle: | http://hdl.handle.net/11571/32594 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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