Cu(I/II) salts or Rose Bengal, used in a catalytic amounts, allow for the mild and easy oxidation of hydroxamic acids to nitrosocarbonyls, using air as final oxidant. These new mild oxidative protocols open new vistas in the field of nitroso Diels-Alder (NDA) and ene reactions (ER) of these fugitive intermediates.

A new life for nitrosocarbonyls in pericyclic reactions

MEMEO, MISAL GIUSEPPE;QUADRELLI, PAOLO
2013-01-01

Abstract

Cu(I/II) salts or Rose Bengal, used in a catalytic amounts, allow for the mild and easy oxidation of hydroxamic acids to nitrosocarbonyls, using air as final oxidant. These new mild oxidative protocols open new vistas in the field of nitroso Diels-Alder (NDA) and ene reactions (ER) of these fugitive intermediates.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11571/702219
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